By Louis D. Quin
An authoritative and finished advent to organophosphorus chemistry The huge, intriguing box of organophosphorus chemistry has grown significantly during the last few a long time, with a wealth of possibilities for learn and functions improvement. A advisor to Organophosphorus Chemistry bargains chemists in academia and whole, up to date insurance of the basics with an eye fixed on destiny advancements during this zone. the world over well-known authority Louis D. Quin extends his skilled point of view and perception at the subject by:* Surveying an important phosphorus-containing useful teams* together with consultant equipment of synthesis, plus references to distinct artificial systems* Outlining advances in stereochemical facets of phosphorus chemistry* protecting parts of present examine, reminiscent of strange coordination states, heterocycles, functions of 31P-NMR, and different spectroscopic tools* offering quite a few references to special overview articles and up to date literature* featuring digital mechanisms and reactive intermediates the place tested* Discussing the significance of phosphorus compounds in residing structures and in agricultural applicationsLiberally illustrated with equations and structural formulation, A advisor to Organophosphorus Chemistry provides an almost extraordinary advent to the subject material, making it an fundamental educational software for aspiring chemists and training chemists alike.
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Additional resources for A Guide to Organophosphorus Chemistry
Comprehensive Heterocyclic Chemistry II, Pergamon Press, Oxford, UK, 1996. 2. -H. -C. Chuang, K. C. -D. Lee, paper presented at the 1998 International Conference on Phosphorus Chemistry, Cincinnati, Ohio, July 1217, 1998. 3. R. Fathi, M. J. Rudolph, R. G. Gentles, R. Patel, E. W. MacMillan, M. S. Reitman, D. Pelham, and A. F. Cook, J. Org. Chem. 61, 5600 (1996). 4. M. M. Rauhut, Top. Phosphorus Chem. 1, 1 (1964); M. Grayson, Pure Appl. Chem. 9, 193 (1964); L. Maier, Fortschr. Chem. Forsch. 19, 1 (1971); C.
Are commonplace. The oxidized products in the past have been assigned oxidation state P(V), and this has led to a description of these products as being pentavalent. They are, however, tetracovalent and are better described in contemporary work as 4-coordinate. In practice, the P(III) to P(V) conversion is generally quite easy, but the reduction of the oxide back to the 3-coordinate form is much more difficult. Procedures for these changes are discussed in appropriate chapters. Another obvious relationship is that between 4-coordinate functional groups with a PH bond and the corresponding oxidized form with POH.
I. J. K. L. M. 1. A. B. C. D. 1. A. Phosphine Oxides 95 4 B. C. D. 1. A. B. C. D. E. F. 1. A. B. C. D. E. F. G. H. I. J. K. A. B. C. D. E. A. B. C. A. B. C. D. E. A. B. C. D. E. A. B. C. D. E. F. Some Major Uses of Organophosphorus Compounds as Reagents in Organic Synthesis 379 References 384 Index 387 Page ix Preface Organophosphorus chemistry is a very broad and exciting field, with many opportunities for research or applications development. This book is my personal reflection, from my 50 years of experience, on the fundamentals of the field and to some extent on where future development might take place.